Publications

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66. Pb(II)-Carboxylate Structure and Reactivity: from Pb(II) Coordination Compounds to PbS Colloidal Nanocrystals
Joshua O. Gibson, Robert A. Brown, Fuyan Ma, Saryvoudh A. Mech, Chenjie Zeng*
Inorg. Chem. 2025, 64, 43, 21592–21602

65. Artificial Atoms by Design
Chenjie Zeng and Sergei A. Ivanov
Nature Synthesis 2025, 4, 1185–1186 
Research Briefing
PDF link

64. Programmable synthesis of atomically precise semiconductor artificial atoms
Fuyan Ma, Sergei A. Ivanov, Lukasz M. Dobrzycki, and Chenjie Zeng*
Nature Synthesis 2025, 4, 1258–1269
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63. Synthesis of a Single PbSe Magic-Sized Cluster: Insights into Reaction Kinetics, Atomic Structure, and Optical Properties
Pranshu Puri, Brian Zhi, Ion Ghiviriga, Lukasz Dobrzycki, Chenjie Zeng*
ACS Nano 2025, 19, 22, 20633–20644

60. From Magic Size to Atomic Precision: Facile Synthesis of a CdTe Semiconductor Nanocluster
Saryvoudh A. Mech, Joshua O. Gibson, Fuyan Ma, Lukasz M. Dobrzycki, and Chenjie Zeng*
J. Am. Chem. Soc. 2025, 147, 9, 7507–7512

59. Bright infrared emitters from cation exchange
Fuyan Ma and Chenjie Zeng*.
Nature Synthesis 2024, 3,1192–1193
PDF link

58. Precision synthesis of a CdSe semiconductor nanocluster via cation exchange
Ma, F.; Abboud, K. A.; Zeng, C*.
Nature Synthesis 2023, 2, 949-959
News Highlight
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57. Nanocluster superstructures assembled via surface ligand switching at high temperature
Johnson, G.; Yang, M. Y.; Liu, C.; Zhou, H.; Zuo, X.; Dickie, D. A.;  Wang, S.; Gao, W.; Anaclet, B.; Perras, F. A.; Ma, F.; Zeng, C.; Wang, D.; Bals, S.; Dai, S.; Xu, Z.; Liu, G.; Goddard III W.A.*; Zhang, S*.
Nature Synthesis 2023, 2, 828-837
PDF link

56. Mapping the Reaction Zones for CdTe Magic-sized Clusters and Their Emission Properties
Mech, S. A.; Ma, F.; Zeng, C*.
Nanoscale, 2023, 15, 114-121.

55. Mass Spectrometry of Au10(4-tert-butylbenzenethiolate)10 Nanoclusters Using Superconducting Tunnel Junction Cryodetection Reveals Distinct Metastable Fragmentation.
Plath, L. D.; Abroshan, H.; Zeng, C.; Kim, H. J.; Jin, R.; Bier, M. E*.
J. Am. Soc. Mass Spectrom. 2022, 33 (3), 521–529.

54. Three-Stage Evolution from Nonscalable to Scalable Optical Properties of Thiolate-Protected Gold Nanoclusters.
Zhou, M.; Higaki, T.; Li, Y.; Zeng, C.; Li, Q.; Sfeir, M. Y.; Jin, R*.
J. Am. Chem. Soc. 2019, 141 (50), 19754–19764.

53. Controlling Magnetism of Au133(TBBT)52 Nanoclusters at Single Electron Level and Implication for Nonmetal to Metal Transition.
Zeng, C.; Weitz, A.; Withers, G.; Higaki, T.; Zhao, S.; Chen, Y.; Gil, R. R.; Hendrich, M.; Jin, R*. 
Chem. Sci. 2019, 10 (42), 9684–9691.

52. Gold Nanoclusters: Bridging Gold Complexes and Plasmonic Nanoparticles in Photophysical Properties.
Zhou, M.; Zeng, C.; Li, Q.; Higaki, T.; Jin, R*.
Nanomaterials 2019, 9 (7), 933.

51. General Synthetic Route to High-Quality Colloidal III–V Semiconductor Quantum Dots Based on Pnictogen Chlorides.
Zhao, T.; Oh, N.; Jishkariani, D.; Zhang, M.; Wang, H.; Li, N.; Lee, J. D.; Zeng, C.; Muduli, M.; Choi, H.-J.; Su, D.; Murray, C. B.*; Kagan, C. R.* 
J. Am. Chem. Soc. 2019, 141 (38), 15145–15152.

50. Au10 (TBBT) 10: The Beginning and the End of Aun(Tbbt)m Nanoclusters.
Zeng, C.; Zhou, M.; Gayathri, C.; Gil, R. R.; Sfeir, M. Y.; Jin, R*. 
Chinese J. Chem. Phys. 2018, 31 (4), 555.

48. Chirality in Gold Nanoclusters. Chiral Nanomaterials: Preparation, Properties and Applications.
Zeng, C.; Wu, Z.; Jin, R*.
John Wiley & Sons, Weinheim 2018, p 99.
(Book Chapter)

47. Ultrafast Relaxation Dynamics of Au38(SC2H4Ph)24 Nanoclusters and Effects of Structural Isomerism.
Zhou, M.; Tian, S.; Zeng, C.; Sfeir, M. Y.; Wu, Z.; Jin, R*. 
J. Phys. Chem. C 2017, 121 (20), 10686–10693.

46. On the Non-Metallicity of 2.2 nm Au246(SR)80 Nanoclusters.
Zhou, M.; Zeng, C.; Song, Y.; Padelford, J. W.; Wang, G.; Sfeir, M. Y.; Higaki, T.; Jin, R*. 
Angew. Chemie Int. Ed. 2017, 56 (51), 16257–16261.

45. Bonding Properties of FCC-like Au44(SR)28 Clusters from X-Ray Absorption Spectroscopy.
Yang, R.*; Chevrier, D. M.; Zeng, C.; Jin, R.; Zhang, P. 
Can.J.Chem. 2017, 95 (August), 1220.

44. Evolution of Excited-State Dynamics in Periodic Au28, Au36, Au44, and Au52 Nanoclusters.
Zhou, M.; Zeng, C.; Sfeir, M. Y.; Cotlet, M.; Iida, K.; Nobusada, K.; Jin, R*. 
J. Phys. Chem. Lett. 2017, 8 (17), 4023–4030.

43. The Largest Crystal Structure of a Gold Nanoparticle to Date-II: Au246(SC6H4Me)80.
Kirschbaum, K.*; Zeng, C.; Chen, Y.; Lambright, K. J.; Jin, R.
Found. Crystallogr. 2017, 73, a359.

42. Chiral Gold Nanoclusters: Atomic Level Origins of Chirality.
Zeng, C.; Jin, R*.
Chem. – An Asian J. 2017, 12 (15), 1839–1850.

41. Surface Engineering of Au36(SR)24 Nanoclusters for Photoluminescence Enhancement.
Kim, A.; Zeng, C.; Zhou, M.; Jin, R*.
Part. Part. Syst. Charact. 2017, 34 (8), 1600388.

40. Oxidation-Induced Transformation of Eight-Electron Gold Nanoclusters: [Au23(SR)16]- to [Au28(SR)20]0.
Higaki, T.; Liu, C.; Chen, Y.; Zhao, S.; Zeng, C.; Jin, R.; Wang, S.; Rosi, N. L.; Jin, R*.
J. Phys. Chem. Lett. 2017, 8 (4), 866–870.

39. Gold Nanoclusters Promote Electrocatalytic Water Oxidation at the Nanocluster/CoSe 2 Interface.
Zhao, S.; Jin, R.; Abroshan, H.; Zeng, C.; Zhang, H.; House, S. D.; Gottlieb, E.; Kim, H. J.; Yang, J. C.; Jin, R*. 
J. Am. Chem. Soc. 2017, 139 (3), 1077–1080.

38. Atomically Precise Gold and Bimetal Nanoclusters as New Model Catalysts.
Zeng, C.; Chen, Y.; Zhao, S.; Jin, R*. 
Stud. Surf. Sci. Catal. 2017, 177, 359–408.
(Book chapter)

37. Emergence of Hierarchical Structural Complexities in Nanoparticles and Their Assembly.
Zeng, C.; Chen, Y.; Kirschbaum, K.; Lambright, K. J.; Jin, R*.
Science 2016, 354 (6319), 1580–1584.

36. Evolution from the Plasmon to Exciton State in Ligand-Protected Atomically Precise Gold Nanoparticles.
Zhou, M.; Zeng, C.; Chen, Y.; Zhao, S.; Sfeir, M. Y.; Zhu, M.; Jin, R*. 
Nat. Commun. 2016, 7 (1), 1–7.

35. Establishing Porosity Gradients within Metal-Organic Frameworks Using Partial Postsynthetic Ligand Exchange.
Liu, C.; Zeng, C.; Luo, T. Y.; Merg, A. D.; Jin, R.; Rosi, N. L*.
J. Am. Chem. Soc. 2016, 138 (37), 12045–12048.

34. Atomically Precise Colloidal Metal Nanoclusters and Nanoparticles: Fundamentals and Opportunities.
Jin, R.*; Zeng, C.; Zhou, M.; Chen, Y.
Chem. Rev. 2016, 116 (18), 10346–10413.

33. Controlling the Crystalline Phases (FCC, HCP and BCC) of Thiolate-Protected Gold Nanoclusters by Ligand-Based Strategies.
Higaki, T.; Zeng, C.; Chen, Y.; Hussain, E.; Jin, R*. 
CrystEngComm 2016, 18, 6979–6986.

32. Characterization of Emissive States for Structurally Precise Au25(SC8H9)18 0 Monolayer-Protected Gold Nanoclusters Using Magnetophotoluminescence Spectroscopy. 
Green, T. D.; Herbert, P. J.; Yi, C.; Zeng, C.; McGill, S.; Jin, R.; Knappenberger Jr, K. L*.
J. Phys. Chem. C 2016, 120 (31), 17784–17790.

31. Atomic Structure of Self-Assembled Monolayer of Thiolates on a Tetragonal Au92 Nanocrystal.
Zeng, C.; Liu, C.; Chen, Y.; Rosi, N. L.; Jin, R*. 
J. Am. Chem. Soc. 2016138 (28), 8710–8713.

30. Controlling the Atomic Structure of Au30 Nanoclusters by a Ligand-Based Strategy.
Higaki, T.; Liu, C.; Zeng, C.; Jin, R.; Chen, Y.; Rosi, N. L.; Jin, R*.
Angew. Chemie Int. Ed. 201655 (23), 6694–6697.

29. Gold Quantum Boxes: On the Periodicities and the Quantum Confinement in the Au28, Au36, Au44, and Au52 Magic Series.
Zeng, C.; Chen, Y.; Iida, K.; Nobusada, K.; Kirschbaum, K.; Lambright, K. J.; Jin, R*.
 J. Am. Chem. Soc. 2016138 (12), 3950–3953.

28. Isomerism in Au28(SR)20 Nanocluster and Stable Structures.
Chen, Y.; Liu, C.; Tang, Q.; Zeng, C.; Higaki, T.; Das, A.; Jiang, D.; Rosi, N. L.; Jin, R*. 
J. Am. Chem. Soc. 2016138 (5), 1482–1485.

26. Gold Tetrahedra Coil up: Kekule-like and Double Helical Superstructures. 
Zeng, C.; Chen, Y.; Liu, C.; Nobusada, K.; Rosi, N. L.; Jin, R*.
Sci. Adv. 20151 (9), e1500425.

25. Crystal Structure of Barrel-Shaped Chiral Au130(p-MBT)50 Nanocluster. 
Chen, Y.; Zeng, C.; Liu, C.; Kirschbaum, K.; Gayathri, C.; Gil, R. R.; Rosi, N. L.; Jin, R*.
J. Am. Chem. Soc. 2015137 (32), 10076–10079.

24. Transformation Chemistry of Gold Nanoclusters: From One Stable Size to Another.
Zeng, C.; Chen, Y.; Das, A.; Jin, R*.
J. Phys. Chem. Lett. 20156 (15), 2976–2986.

23. Observation of Body-Centered Cubic Gold Nanocluster.
Liu, C.; Li, T.; Li, G.; Nobusada, K.; Zeng, C.; Pang, G.; Rosi, N. L.; Jin, R*. 
Angew. Chem. Int. Ed. 201554 (34), 9826–9829.

22. Efficient Electrochemical CO2 Conversion Powered by Renewable Energy.
Kauffman, D. R.*; Thakkar, J.; Siva, R.; Matranga, C.; Ohodnicki, P. R.; Zeng, C.; Jin, R. 
ACS Appl. Mater. Interfaces 20157 (28), 15626–15632.

21. Tuning the Magic Size of Atomically Precise Gold Nanoclusters via Isomeric Methylbenzenethiols.
Chen, Y.; Zeng, C.; Kauffman, D. R.; Jin, R*.
Nano Lett. 201515 (5), 3603–3609.

20. Structural Patterns at All Scales in a Nonmetallic Chiral Au133(SR)52 Nanoparticle.
Zeng, C.; Chen, Y.; Kirschbaum, K.; Appavoo, K.; Sfeir, M. Y.; Jin, R*.
Sci. Adv. 20151 (2), e1500045.

18. Role of Au4 Units on the Electronic and Bonding Properties of Au28(SR)20 Nanoclusters from X-Ray Spectroscopy.
Chevrier, D. M.; Zeng, C.; Jin, R.; Chatt, A.; Zhang, P*.  
J. Phys. Chem. C 2015119 (2), 1217–1223.

17. Temperature-Dependent Photoluminescence of Structurally-Precise Quantum-Confined Au25(SC8H9)18 and Au38(SC12H25)24 Metal Nanoparticles.
Green, T. D.; Yi, C.; Zeng, C.; Jin, R.; McGill, S.; Knappenberger, K. L*.
J. Phys. Chem. A 2014, 118, 10611–10621.

16. Gold–Thiolate Ring as a Protecting Motif in the Au20(SR)16 Nanocluster and Implications.
Zeng, C.; Liu, C.; Chen, Y.; Rosi, N. L.; Jin, R*.
J. Am. Chem. Soc. 2014, 136, 11922–11925.

15. Probing Active Site Chemistry with Differently Charged Au25q Nanoclusters (q = −1, 0, +1).
Kauffman, D*. R.; Alfonso, D.; Matranga, C.; Ohodnicki, P.; Deng, X.; Siva, R. C.; Zeng, C.; Jin, R.
Chem. Sci. 2014, 5, 3151.

14. Generation of Singlet Oxygen by Photoexcited Au25(SR)18 Clusters.
Kawasaki, H.*; Kumar, S.; Li, G.; Zeng, C.; Kauffman, D. R.; Yoshimoto, J.; Iwasaki, Y.; Jin, R*.
Chem. Mater. 2014, 26, 2777–2788.

13. Gold Nanoclusters: Size-Controlled Synthesis and Crystal Structures.
Zeng, C.; Jin, R*.
In Structure and Bonding; 2014; Vol. 119, pp 193–223.
(Book Chapter)

12. Thiolate Ligands as a Double-Edged Sword for CO Oxidation on CeO2 Supported Au25(SCH2CH2Ph)18 Nanoclusters.
Wu, Z.*; Jiang, D.; Mann, A. K. P.; Mullins, D. R.; Qiao, Z.-A.; Allard, L. F.; Zeng, C.; Jin, R.; Overbury, S. H*.
 J. Am. Chem. Soc. 2014, 136, 6111–6122.

11. Magic Size Au64(S-c-C6H11)32 Nanocluster Protected by Cyclohexanethiolate.
Zeng, C.; Chen, Y.; Li, G.; Jin, R*.
Chem. Mater. 2014, 26, 2635–2641.

10. Crystal Structure and Electronic Properties of a Thiolate-Protected Au24 Nanocluster.
Das, A.; Li, T.; Li, G.; Nobusada, K.; Zeng, C.; Rosi, N. L.; Jin, R*.
Nanoscale 2014, 6, 6458.

9. Cyclopentanethiolato-Protected Au36(SC5H9)24 Nanocluster: Crystal Structure and Implications for the Steric and Electronic Effects of Ligand.
Das, A.; Liu, C.; Zeng, C.; Li, G.; Li, T.; Rosi, N. L.; Jin, R*. 
J. Phys. Chem. A 2014, 118, 8264–8269.

6. CeO2-Supported Au38(SR)24 Nanocluster Catalysts for CO Oxidation: A Comparison of Ligand-on and -off Catalysts.
Nie, X.; Zeng, C.; Ma, X.; Qian, H.; Ge, Q.*; Xu, H.; Jin, R*.
Nanoscale 2013, 5, 5912.

5. Nonsuperatomic [Au23(SC6H11)16]− Nanocluster Featuring Bipyramidal Au15 Kernel and Trimeric Au3(SR)4 Motif.
Das, A.; Li, T.; Nobusada, K.*; Zeng, C.; Rosi, N. L.; Jin, R*.
J. Am. Chem. Soc. 2013, 135, 18264–18267.

4. Unique Bonding Properties of the Au36(SR)24 Nanocluster with FCC-like Core.
Chevrier, D. M.; Chatt, A.; Zhang, P.*; Zeng, C.; Jin, R.
J. Phys. Chem. Lett. 2013, 4, 3186–3191.

3. Chiral Structure of Thiolate-Protected 28-Gold-Atom Nanocluster Determined by X-Ray Crystallography.
Zeng, C.; Li, T.; Das, A.; Rosi, N. L.; Jin, R*.
J. Am. Chem. Soc. 2013, 135, 10011–10013.

2. Thiol Ligand-Induced Transformation of Au38(SC2H4Ph)24 to Au36(SPh-t-Bu)24.
Zeng, C.; Liu, C.; Pei, Y.; Jin, R*.
ACS Nano 2013, 7, 6138–6145.

1. Total Structure and Electronic Properties of the Gold Nanocrystal Au36(SR)24.
Zeng, C.; Qian, H.; Li, T.; Li, G.; Rosi, N. L.; Yoon, B.; Barnett, R. N.; Whetten, R. L.; Landman, U.; Jin, R*.
Angew. Chem. Int. Ed. 2012, 51, 13114–13118.